The absolute configuration of ( )-3-hydroxy-a-calacorene
نویسندگان
چکیده
3-Hydroxy-a-calacorene was identified in extracts from cold-shocked seedlings of cotton (Gossypium hirsutum L.) and kenaf (Hibiscus cannabinus L.), both of which are members of the Malvaceae family. ( )-3-Hydroxy-a-calacorene was isolated from Heterotheca inuloides Cass. (Asteraceae). HPLC on a chiral stationary phase column showed that the 3-hydroxy-acalacorene from cotton and kenaf had the same relative configuration, while that from H. inuloides was of the opposite configuration. X-ray crystallographic analysis established the absolute configuration of the compound in H. inuloides as (8R)-( )-3-hydroxy-a-calacorene. 2006 Elsevier Ltd. All rights reserved.
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